Hi, this could be very easy or very simple to mention, but believe me some times simple things are easy to miss.

1) As i mentioned is it very easy. Just click “List” tab on the “List Tools” and you will see “Customize Form” button, click this and it will open InfoPath, there you go.

2) This method is actually unnecessary but just know that there is another way. Click “List” tab on the “List Tools” and you will see “List Settings” button, click this and it will open “List Information” page. In this page you will see “Form Setting”. When you click form setting you will see form option, if you click OK button again it will open InfoPath to edit.

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This is the default form template

This is edited form template

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